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NEET-UG and JEE Main Chemistry · Class 12

Werner's theory — NEET & JEE Questions

Werner's theory is a topic in Coordination Compounds, a Class 12 Chemistry chapter of the NEET-UG and JEE Main syllabus. TestBudy holds 12 published NEET-UG and JEE Main questions on Werner's theory, each with the marking scheme of the real paper.

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Werner's theory MCQs with solutions

10 of the 12 published questions on this topic, exactly as they appear in a test. Answers and worked solutions come with your result rather than on this page.

  1. Question 1 · difficulty L1 · recall

    In Werner's theory, the primary valency of a metal in a coordination compound corresponds to its

    • A. oxidation state
    • B. coordination number
    • C. number of lone pairs
    • D. magnetic moment
  2. Question 2 · difficulty L2 · understanding

    Werner's secondary valency corresponds most closely to the

    • A. coordination number
    • B. oxidation state only
    • C. atomic number
    • D. mass number
  3. Question 3 · difficulty L2 · understanding

    According to Werner's theory, secondary valencies are

    • A. directional and determine geometry
    • B. non-directional and unrelated to geometry
    • C. satisfied only by anions outside the coordination sphere
    • D. always equal to the oxidation state
  4. Question 4 · difficulty L2 · understanding

    In a coordination formula, species written inside square brackets belong to the

    • A. coordination sphere
    • B. outer ionisation sphere only
    • C. solvent only
    • D. crystal lattice but not the complex
  5. Question 5 · difficulty L3 · application

    For [Co(NH3)6]Cl3[Co(NH_3)_6]Cl_3, what is the coordination number of cobalt?

    • A. 3
    • B. 4
    • C. 6
    • D. 9
  6. Question 6 · difficulty L3 · application

    In [Co(NH3)6]Cl3[Co(NH_3)_6]Cl_3, what is the oxidation state of cobalt?

    • A. 0
    • B. +1
    • C. +2
    • D. +3
  7. Question 7 · difficulty L3 · application

    Which ions are produced outside the coordination sphere when [Co(NH3)6]Cl3[Co(NH_3)_6]Cl_3 dissolves in water?

    • A. Three Cl−Cl^- ions
    • B. Six NH3NH_3 ions
    • C. Three NH3+NH_3^+ ions
    • D. No ions
  8. Question 8 · difficulty L3 · application

    For [Co(NH3)5Cl]Cl2[Co(NH_3)_5Cl]Cl_2, how many chloride ions are outside the coordination sphere?

    • A. 1
    • B. 2
    • C. 3
    • D. 5
  9. Question 9 · difficulty L4 · application

    A cobalt complex of formula CoCl3⋅6NH3CoCl_3\cdot6NH_3 gives three moles of AgClAgCl precipitate per mole of complex with excess AgNO3AgNO_3. Which Werner formulation is most consistent?

    • A. [Co(NH3)6]Cl3[Co(NH_3)_6]Cl_3
    • B. [Co(NH3)5Cl]Cl2[Co(NH_3)_5Cl]Cl_2
    • C. [Co(NH3)4Cl2]Cl[Co(NH_3)_4Cl_2]Cl
    • D. [Co(NH3)3Cl3][Co(NH_3)_3Cl_3]
  10. Question 10 · difficulty L4 · application

    A compound CoCl3⋅5NH3CoCl_3\cdot5NH_3 produces two moles of AgClAgCl per mole with excess AgNO3AgNO_3. Which coordination formula fits?

    • A. [Co(NH3)6]Cl3[Co(NH_3)_6]Cl_3
    • B. [Co(NH3)5Cl]Cl2[Co(NH_3)_5Cl]Cl_2
    • C. [Co(NH3)4Cl2]Cl[Co(NH_3)_4Cl_2]Cl
    • D. [Co(NH3)3Cl3][Co(NH_3)_3Cl_3]

Common mistakes in Werner's theory

Recorded against questions in this topic that are not shown above, so none of these points at an answer you can see on this page.

  • Interchanges the meanings of primary and secondary valency.
  • Uses empirical composition alone and ignores how precipitation identifies chloride ions outside the coordination sphere.

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